I think this could be your man: Charles Duret de Chevry de La Boulaye, born ca 1645, in France. In his biography, we learn that he was lieutenant for the king in Acadia 1685-1690. The establishment of the company at Chedabouctou then consisted of Fort Saint-Louis and several roughly built huts. la Boulaye had 15 or 20 hired men with him there. There is no wife or children listed for him in Stephen White's Dictionnaire p. 891.
Historian and professor Nicolas Landry also mentions him in this article, and cites the biography mentioned above, p. 12 of 34.
I don't believe that a profile has been created for him yet although it is hard to search with so many names. I would use Duret for his Last Name at Birth, and put de La Boulaye, de la Boulais, de Chevry in Other Last Names.